The announcer introduced the show by saying: "Its time again for Pokémon Entertainment Show! We'll get you the latest news and movie information, right here on Pokémon Smash!". The episode started with Professor Red and Golgo talking until Shoko-tan comes running in. They wonder what's wrong and she says she has 'big news!' and that she had the title of the new Pocket Monsters movie. The International division girls show up and then say there is a new Pokémon going to be in the new movie. Robert then run in and Golgo asks if they had any news about the new movie but Baba is confused as they don't hae any news.

Yamamoto then introduced this weeks rerun episode as part of the Pokémon Library. The theme for the episode was: Memories are treasures you keep for life (思い出は一生の宝物). This weeks Pokémon Library rerun episode was Sohnano!? Gym Badges and Sonansu!! (ソーナノ!?ジムバッジとソーナンス!!) from the original series. A full summary of that episode is available in the episode guide. Professor Red said his go-to line 'OK! Pokémon Library!' to start the repeat episode.


After the Pokémon Library, Shoko-tan announced the full title for the 15th Pocket Monsters movie as Kyurem VS the Sacred Swordsman Keldeo (キュレムVS聖剣士ケルディオ). She also revealed the full details for the Legendary Pokémon Keldeo (ケルディオ). A scoop video showing scenes from the upcoming movie were also shown.


The Adventure division then annoucned their VTR for the week which featured Robert sneaking into the Production Site of Pokémon + Nobunaga's Ambition. Yamamoto showed up dressed up like the male protagonist in the game. Pokémon + Nobunaga's Ambition (ポケモン＋ノブナガの野望) is mix of the two gaming series: Pokémon and Nobunaga's Ambition. With Yamamoto leading the charge to find out information about the game, a screen appeared showing a modified box art of Hiroshi's Ambition （ヒロシの野望).


Robert then head off to Koei Tecmo where the game was being developed. They walked into a meeting and the producer Hisashi Koinuma (鯉沼久史) met with Robert who agreed to show them some things about the new game. The first point in Hiroshi's Ambition information discovery was: I want to know about the characters!(登場人物についてしりたい！). Koinuma explained that the main characters in the game are officers (ブショー), people possessing specials bonds with Pokémon. The protagonist, as the officer leader of Hajime Province, becomes involved in the unfolding war of the many strong leaders, led by Nobunaga, who seek to cause the downfall of Ranse. The CG Artist for the game, Masayuki Tanimoto (谷本将之) then showed off some of the artwork for these officers.


Koinuma then explained that the protagonists could evolve and their outfits changed as a result. Not only that, but the officers could also evolve as well as their outfits changed and their Pokémon could also evolve into a Pokémon in their evolution chain.


The second point in Hiroshi's Ambition information discovery was: I would like to inspect a company! (会社を見学したい！). Rober then went outside and looked around the building. They then noticed a large tile mural in the courtyard of the building. They then went to the sound room and Yamamoto did his own voiceover for the games commercial.

The third point in Hiroshi's Ambition information discovery was: Play Pokémon + Nobunaga's Ambition for TV! (テレビ初ポケモン＋ノブナガの野望をプレイ！). The producer and the other staff members discussed it for a bit and they agreed to let Yamamoto play the game. Game Director Osamu Saigusa (三枝修) was then introduced and Yamamoto began by entering his name for the game. While playing, Saigusa explained that the game is based on the officers who fight for supreme control of the 17 provinces that make up the Ranse Region (ランセ地方). Oichi was introduced and she is a mysterious, pretty officer girl who arrived in Hajime Province, supporting the protagonist for unknown reasons. Her Partner Pokémon is Purin.

After playing the game a bit and showing it off, 6-on-6 player battles were introduced and Koinuma battled against Yamamoto. The first battle didn't go well for Yamamoto and he ended up being beat by Koinuma. In the next match, since Koinuma had the advantage as he knew more about the game, they gave Yamamoto 6 Pokémon to battle with while Koinuma only had 4 Pokémon. Yamamoto ended up winnning that round.


As a parting gift for Robert, Koinuma have them a poster that was based in the Nobunaga's Ambition with Robert in it. The announcer also reminded the viewers that those that order the game also would receive the a special Rayquaza card.


For the studio audience battle 8 year old Mayu Yonekawa (米川真由) battled against Yamamoto but being one of the Smash Elite Four members, Yamamoto showed he was a formidable opponent and he defeated her.