The announcer introduced the show by saying: "All right today we'll going to feature Pokémon Quiz Caravan and a lot more! It's all happens right here! Pokémon Smash!". Golgo started off by saying that on November 6th, 1947, Japan's first mass group date matchmaking was done (１９４７年　日本で初めて集団でのお見合いが行われたひ).


They then decide to do a matchmaking party for 26 year old Shoko-tan. First up was Akiyama who presented Professor Akido. Then Golgo revealed a picture of Golgo+Baba from Pokémon Sunday #261. Yamamoto then presented Yamamoto Victini. Shoko-tan didn't really want to make a decision about any of the selections though.


Baba introduced this weeks rerun episode as part of the Pokémon Library and she also announced this weeks theme, Looks can be deceiving (人は見かけによらない). This weeks Pokémon Library rerun episode was Gardie and Kojiro (ガーディとコジロウ) from the original series. A full summary of that episode is available in the episode guide. Professor Red said his go-to line 'OK! Pokémon Library!' to start the repeat episode.

After the Pokémon Library episode, Yamamoto Victini showed up. He started off by saying the corny joke: "You all seem cold. You're not catching a cold, are you?" (みなさん寒くなってきたけどカゼとかひいてない？) which got Misaki and Shoko-tan laughing hard. Yamamoto Victini then changed the "V" on its head upside down to make a "へ". へ indicates direction or goal. Yamamto Victini then challenged them to do the Victini Relay Quiz with the "V" as a "へ" which meant the "V" was upside down when trying to hold the balls in.


The first part of the relay, Maria had to stack a can on top of one another. She kept one hand on one end of the balls but needed the other hand free to stack the can so some of the balls came out. Baba had to just walk across the room to Akiyama so he decided to crawl through his legs so the 'V' was rightside up and the balls wouldn't fall out. Akiyama then had to put on a skirt and he managed to do so by wiggling his legs and hips but just as he did so and adjusted it a bit, all the balls fell out.


The VTR of Golgo and Red doing a Quiz Caravan then played. For this Pokémon Quiz Caravan, Red and Golgo visited Wada Suginami, Elementary School, Tokyo (東京都　杉並区立　和田小学校). Golgo and Red went into a Computer Lab where all the kids were playing the new PC game "Pokémon PC Challenge" (ポケモンPCチャレンジ) which helps people learn to type better.


This time 78 grade 4 students participated in the Pokémon Quiz Caravan. The first segment of the quiz was the 'Black/White Quiz' (ブラックホワイトクイズ). The kids were all on their own this time but were also divided up into two main groups and they would move to either the Black (X) or White (O) side of the gym when the questions were asked.
Below are the questions that were asked in Round 1:

#	Question	Answer
1	Game - In Hiun City, players can take the blue boat to the United Tower (ヒウンシティにある青い船にのるとユナイテッドタワーにいける)	(O) Yes Spoiler: Click to show!
2	Pokémon Smash - Yamamoto is the leader of the Adventure Division (アドベンチャー部のリーダーは山本隊員である)	(X) No, Director Zoroark is the leader of the Adventure Division Spoiler: Click to show!

Below are the questions that were asked in Round 2:

#	Question	Answer
1	Game - Kojondo is the Kung Fu Pokémon (コジョンドはカンフーポケモンである)	(X) No - Martial Arts Pokémon (ぶじゅつポケモン) Spoiler: Click to show!
2	Game - In Pocket Monsters Black, the 8th badge Gym Leaders name is Jaga (ボゲットモンスターブラック8荷目のバッジのジムリーダーの名前はジャガである)	(X) No - It's Shaga (シャガ) Spoiler: Click to show!

Black team won the first round and got 30 points while the White Team won second round and got 20 points. The next portion of the quiz was Iwapalace's Letter Sorting Quiz (イワパレスの文字ならべかえクイズ）. 5 team members would have a letter placed on their back and the other team members would have to tell them which order they needed to go into to spell a Pokémon's name. They would crawl around until they got it right.


Below are the Pokémon names that were rearranged in the quiz:

#	Letters	Answer
1	カジブメキ	Mebukijika (メブキジカ) Spoiler: Click to show!
2	マルチフタ	Futachimaru (フタチマル) Spoiler: Click to show!
3	イカラブゼ	Zebraika (ゼブライカ) Spoiler: Click to show!
4	ッナーヤキ	Yanakkie (ヤナッキー) Spoiler: Click to show!
5	ライタンク	Kuitaran (クイタラン) Spoiler: Click to show!
6	ストロルボ	Voltolos (ボルトロス) Spoiler: Click to show!
7	カッチラマ	Maracacchi(マラカッチ) Spoiler: Click to show!
8	インダキケ	Daikenki (ダイケンキ) Spoiler: Click to show!
9	フーエルン	Elphoon (エルフーン) Spoiler: Click to show!
10	クーロアゾ	Zoroark (ゾロアーク) Spoiler: Click to show!
11	ドコツッテ	Dotekkotsu (ドテッコツ) Spoiler: Click to show!

Black team was now winning with 80 points and White team had 50 points. The next portion of the quiz was the Victini's V-Generate　Find the Mistake Obstacle Course Quiz (ビクティニのＶジェネレート障害物まちがいさがしクイズ). Participants would wear a helmet with a V shaped container that had balls in them. They would have to go through the obstacle course while trying not to drop the balls. The first part was finding a candy ball in a flour pan, the second part was looking in a mirror to put balls in the V helmet, the third part was popping a balloon and the final part was group skipping. For each ball that they had left at the end of the obstacle course, the team would get 1 second on the clock.


Black team ended up winning the quiz caravan with 170 points while white team ended up with 130 points. 10 year old Yui Tezuka (手塚結衣) was up to battle a Smash Elite Four member. She battle against Yamamoto and almost ended up beating him but Yamamoto was barely able back in the end.